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Definition of -Ylidene

What does -Ylidene mean?


  1. [organic chemistry] Forms the names of divalent radicals or groups connected through a carbon double bond

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Google previewSynthetic and Mechanistic Organic Electron Transfer Reactions (2010)

by T. Fuchigami

Imidazole-2-ylidene is a singlet carbene, quite stable as it is stabilized by the two π-donor nitrogen atoms (Figure 1), so it behaves as nucleophile or base, rather than a diradical (9). N N R R' Figure 1. Stabilization of the singlet state of NHC.

Google previewScience of Synthesis Knowledge Updates 2013 (2014)

by Klaus Banert, Jozef Drabowicz

1,3-di-tert-butylimidazol-2-ylidene is a facile route to cyclic silylenes 27 ( Scheme 18).[29] This method can be applied for the generation of stable and transient four- and five-membered heterocyclic silylenes under mild conditions in the ...

Google previewPalladium in Organic Synthesis (2005)

by Jiro Tsuji

It is interesting to note that NHC with very small methyl substituents on the nitrogens are reported to be relatively stable liquids and l,3,4,5- tetramethylimidazol-2-ylidene is a stable crystalline material [19]. It can be concluded that the electronic ...

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