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Definition of -Ylidene
What does -Ylidene mean?
- [organic chemistry] Forms the names of divalent radicals or groups connected through a carbon double bond
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by Tse-Lok Ho
Electron properties and stability of imidazole-based mesionic carbenes ( imidazol-5-ylidenes) are found to be inversely correlated.2 stable precursors of NHC's.3 1,3-Bis(2,6dimethoxyphenyl)imidazol-2-ylidene is a typical electronrich ...
by T. Fuchigami
Imidazole-2-ylidene is a singlet carbene, quite stable as it is stabilized by the two π-donor nitrogen atoms (Figure 1), so it behaves as nucleophile or base, rather than a diradical (9). N N R R' Figure 1. Stabilization of the singlet state of NHC.
by Jiro Tsuji
It is interesting to note that NHC with very small methyl substituents on the nitrogens are reported to be relatively stable liquids and l,3,4,5- tetramethylimidazol-2-ylidene is a stable crystalline material . It can be concluded that the electronic ...
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