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Examples of allylic

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13 examples:

Allylic oxidations have featured in hundreds of syntheses, including some natural product syntheses regarded as “classics”.
(Nature, )

Here we report the use of both photoredox and organic catalysis to accomplish a mild, broadly effective direct allylic C–H arylation.
(Nature, )

These requirements are problematic in industrial settings; currently, no scalable and sustainable solution to allylic oxidation exists.
(Nature, )

Palladium catalyzed allylic substitution reactions typically proceed via an outer sphere mechanism, yielding predominately linear products.
(Nature Communications, )

Here, the authors report an inner sphere process for the allylic substitution of ketone enolates, giving branched products with up to three contiguous stereocentres.
(Nature Communications, )

Within this context, the discovery of chemical transformations that are able to directly functionalize allylic methyl, methylene and methine carbons in a catalytic manner is a priority.
(Nature, )

Here, the authors show a catalytic asymmetric process for the addition of sulphur ylides to cyclic allylic esters with loss of CO 2, giving access to chiral, highly functionalised indolines.
(Nature Communications, )

Here, the in situ preparation of reactive allylic and benzylic boronic acids, obtained by reacting flow-generated diazo compounds with boronic acids, and their application in controlled iterative C–C bond forming reactions is described.
(Nature Chemistry, )

In particular, the direct arylation of non-functionalized allylic systems would enable access to a series of known pharmacophores (molecular features responsible for a drug’s action), though a general solution to this long-standing challenge remains elusive.
(Nature, )

It uses inexpensive and readily available materials, and represents a scalable allylic C–H oxidation (demonstrated on 100 grams), enabling the adoption of this C–H oxidation strategy in large-scale industrial settings without substantial environmental impact.
(Nature, )

A persisting problem, however, is the dearth of chemical transformations that directly generate acyclic Z allylic alcohols, including products that contain a hindered neighbouring substituent or reactive functional units such as a phenol, an aldehyde, or a carboxylic acid.
(Nature, )

The oxidation of allylic systems has played a prominent role in this context as possibly the most widely applied C–H functionalization, owing to the utility of enones and allylic alcohols as versatile intermediates, and their prevalence in natural and unnatural materials.
(Nature, )

Although protocols for direct oxidation and amination of allylic C–H bonds (that is, C–H bonds where an adjacent carbon is involved in a C = C bond) have become widely established, the engagement of allylic substrates in C–C bond forming reactions has thus far required the use of pre-functionalized coupling partners.
(Nature, )

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